Quartic versus Hyperbolic Double Wells
The quartic well and the Razavy well look alike on the real axis: below the barrier, each has two allowed islands separated by an open forbidden path. That resemblance is useful only after the coordinate, barrier height, kinetic scale, and energy have been matched.
Once both minima are placed at and both barriers have height one, the comparison becomes exact:
At a common normalized kinetic scale , the first statement orders the indexed eigenvalues. The second gives a controlled local quartic limit of the hyperbolic well, not uniform convergence on . Neither statement makes the global ODEs identical: polynomial infinity and the two irregular ends of a DCHE problem retain different Stokes and connection data.
One barrier-normalized passport makes comparison meaningful
Section titled “One barrier-normalized passport makes comparison meaningful”Use the common spectral problem
Here the minima are at , the central barrier is , and measures kinetic energy relative to the chosen separation and barrier.
For the quartic convention of Page 3, set
Multiplying its eigenvalue equation by gives
For Razavy, write
in the double-well chamber . Division by the barrier gives
where
The dictionary is therefore
| Datum | Quartic | Razavy |
|---|---|---|
| Shape | ||
| Kinetic scale | ||
| Energy | ||
| Shape parameter | none |
Raw energies or raw barrier actions from the two pages should not be placed in one ratio. A matched comparison means the same in the normalized operators. Choosing is a comparison protocol, not a universal identity between and .
The normalized hyperbolic shape lies above the quartic
Section titled “The normalized hyperbolic shape lies above the quartic”The ordering follows from the power series of . Put . For ,
whereas the inequality reverses for . In both ranges,
Squaring proves
Equality holds at the barrier and minima, , but is strict elsewhere. Thus barrier- and separation-matched hyperbolic wells are everywhere no lower than the quartic well.
Their local curvatures sharpen the picture:
For , the normalized hyperbolic barrier is flatter at its top and its minima are steeper. Between the three matching points its barrier sits higher.
On every fixed compact set,
The bracketed form means
Left: after matching minima and barrier height, the Razavy shapes lie at or above the quartic shape and approach it as . Right: the dimensionless bottom action starts at and approaches as the hyperbolic well becomes increasingly steep away from its minima.
Expert checkpoint: spectral ordering and convergence
At fixed , form ordering and the min–max principle give
For strictness, put and with any . The bounded function is positive almost everywhere. Along
one-dimensional bound-state eigenvalues are simple, so the Hellmann–Feynman identity gives
Since , a second use of min–max proves the displayed strict inequality for every .
The pointwise limit is not uniform on the whole line: polynomial and exponential tails never become the same at fixed . Nevertheless, for each fixed and ,
The lower bound is the form ordering. For the upper bound, smoothly cut off the first quartic eigenfunctions outside a large compact interval and use uniform convergence of on that interval in the min–max trial space. The cutoff error is made small before is taken.
Four real turning points share one separatrix skeleton
Section titled “Four real turning points share one separatrix skeleton”Let . For the quartic shape,
For the hyperbolic shape,
In either model the ordered real roots are
The outer pairs bound two equal allowed intervals; the inner pair bounds the forbidden barrier. At , the inner roots collide at . Above the barrier, only the outer pair remains real. Expanding the hyperbolic formulas at small recovers the quartic formulas.
Four roots alone do not guarantee a narrow doublet. Near a minimum, the local harmonic energies measured in units of the barrier are
The diagnostic places a fixed local level well below the separatrix. It is not an error bound. When approaches one, the inner turning points coalesce and a uniform Weber (parabolic-cylinder) barrier-top analysis replaces a dilute-instanton expansion.
Equal barriers do not mean equal tunnelling actions
Section titled “Equal barriers do not mean equal tunnelling actions”For a barrier-normalized shape define the open bottom action
The quartic value is
For Razavy,
The shape inequality gives
and direct expansion yields
The normalized exponents reproduce the raw actions on the two earlier pages:
The Razavy expression has two useful physical limits. With ,
whereas
For model , define the positive odd–even gap of the th doublet by
At matched , fixed , and fixed , the leading comparison is
This orders the leading exponential scales, not the exact finite- splittings. Form ordering of individual eigenvalues does not order a difference of two eigenvalues. The quartic determinant prefactor and loop coefficients from Page 3 cannot be transplanted to Razavy.
A coalescing-well limit produces the quartic operator
Section titled “A coalescing-well limit produces the quartic operator”The local limit becomes transparent if
is held fixed. Since , this means
Then
so that
on every fixed -window. The Page 3 quartic has
The action limit is automatic:
This is a singular double scaling. Indeed,
Taking at fixed instead collapses the barrier and sends to infinity; it does not retain a finite quartic quantum problem.
The Page 5 benchmark has , so it is deliberately far from this threshold scaling.
Fixed produces a finite quartic quantum operator. To make that operator semiclassical as well, one needs . In terms of , simultaneous shape convergence and a deep-well limit require
These conditions use the Page 5 convention . If the scaling is tuned through integer values of , the invariant-space dimension grows with . Although any fixed low level can be followed inside these growing algebraic sectors, the representation does not stabilize to a fixed-dimensional invariant polynomial space for the limiting quartic operator.
The global analytic passports remain different
Section titled “The global analytic passports remain different”The quartic limit is local in the scaled coordinate. It does not erase the following global distinctions.
| Datum | Quartic completion | Hyperbolic completion |
|---|---|---|
| Real tail | ||
| WKB growth | ||
| Turning points | four finite points in the -plane | infinitely repeated in , four on the exponential cylinder |
| Irregular ends | sectors of one polynomial infinity | two distinct ends |
| Canonical scalar form | quartic Schrödinger normal form with one polynomial irregular infinity | DCHE after |
| Finite algebra used here | none | first states when |
For Razavy, define
This is quartic in , but the WKB differential is
For the normalized quartic,
Both compactified branch curves are generically genus one. Genus does not determine a connection problem. On the quartic curve, has a fourth-order pole at each of the two points above . On the Razavy curve, has a second-order pole at each of the two points above and each of the two points above . Thus the pole divisors differ: two fourth-order poles over one base endpoint versus four second-order poles over two base endpoints.
There is also a complex Razavy collision at
in addition to the real barrier collision at . As , the imaginary period of the hyperbolic shape recedes from every compact -window, but the finite- DCHE problem is not globally conjugate to the quartic polynomial-infinity problem.
Geometry, QES, and exact WKB answer different questions
Section titled “Geometry, QES, and exact WKB answer different questions”In the normalized variables, every and corresponds to
The Razavy operator is QES only on the curves
That arithmetic condition neither creates the double-well shape nor makes a sub-barrier pair narrow. It merely closes the finite polynomial block derived on Page 5.
Choose the method from the question:
- Deep quartic, fixed local level. Use the instanton/transseries quantization of Page 3 and audit it with its independent Galerkin and coordinate-space spectra.
- Generic Razavy below the barrier. Use a DCHE connection determinant or exact WKB, then check with a parity-resolved coordinate solver.
- Integer Razavy, first states. Use the finite Jacobi block as an exact calibration and check it independently against the full operator.
- Near either separatrix. Use a uniform Weber treatment for coalescing turning points; a fixed-level dilute-instanton expansion is not uniform.
- Above the barrier. Use the two-real-turning-point problem and stop calling adjacent levels a tunnelling doublet.
Detuning integer does not remove parity, the boundary problem, or the exact-WKB construction; only the finite block disappears. Away from discriminants and Stokes walls, chosen turning points and cycles continue analytically, although the Stokes graph may still wall-cross. Page 7, Quasi-exact solvability versus generic exact-WKB behavior, isolates that separation. Page 8, Three controlled capstones, will use recurrence, direct numerics, and exact WKB as genuinely independent checks.
Common pitfalls
Section titled “Common pitfalls”Comparing raw numbers before normalizing. The two earlier pages use different coordinates, barriers, kinetic terms, and energy units. Match the passport before comparing levels, actions, or splittings.
Treating four real roots as proof of a doublet. Four roots establish a sub-barrier topology. Exponentially narrow splitting additionally requires a small normalized kinetic scale at fixed local level.
Using a bottom action as a finite-energy answer. The displayed actions are exact at the well bottom. A finite-energy splitting requires the energy-dependent inner cycle and model-specific fluctuation data.
Turning a local limit into a global Heun identity. The normalized Razavy potential converges to the quartic on compact scaled regions. Its finite- endpoint singularities and Stokes data remain different.
Using QES as a synonym for semiclassical. Integer is an algebraic closure condition. It does not imply a high barrier, a narrow doublet, or a terminating WKB series.
Exercises
Section titled “Exercises”1. Build the common passport
Section titled “1. Build the common passport”Starting from the operators on Pages 3 and 5, derive , , , and .
Solution
For the quartic problem, gives and . Multiplication by produces
Hence
For Razavy, and . The barrier is in square-root units. Division by its square gives
2. Prove the shape ordering and compare curvatures
Section titled “2. Prove the shape ordering and compare curvatures”Use the power series of to prove , then differentiate at .
Solution
With , every coefficient in
is positive. For , ; for , . Comparing with and taking the correct absolute value on each side of gives
Squaring proves the claim. Direct differentiation gives
The quartic values are and .
3. Recover the turning-point limit and depth tests
Section titled “3. Recover the turning-point limit and depth tests”Derive both pairs of positive turning points at normalized energy , and show that the hyperbolic pair tends to the quartic pair as .
Solution
The quartic equation
gives . For Razavy,
Taking the positive inverse hyperbolic cosine gives the displayed inner and outer roots. Since
and , the quartic roots follow.
Near a minimum, . Here
The local level is , which yields the two depth diagnostics in the text.
4. Compare the two bottom actions
Section titled “4. Compare the two bottom actions”Evaluate and derive its small- limit. Then recover the near-threshold form of the raw Razavy action.
Solution
Inside the barrier,
Integration gives
For the raw action, put . From
one has . Also,
Substitution yields
5. Take the controlled quartic limit
Section titled “5. Take the controlled quartic limit”Hold fixed as . Derive the limiting operator and match its action to the Page 3 exponent.
Solution
The rescaled Razavy operator is exactly
Local uniform convergence of the shape gives
Multiplying the normalized quartic problem by shows that . Therefore
which is the one-instanton exponent on Page 3.
6. Show why equal genus is insufficient
Section titled “6. Show why equal genus is insufficient”Derive the quartic equation for the Razavy turning points in and its WKB differential. Compare it with the normalized quartic curve.
Solution
Since
one finds
Thus the numerator can be denoted by , and
Both and are quartic branch curves and are generically genus one. On the compact quartic curve, has fourth-order poles at the two points above . On the compact Razavy curve, has second-order poles at the two points above and the two points above . Therefore the genera agree while the pole divisors, periods, and connection data need not.
7. Separate geometry, QES, and method choice
Section titled “7. Separate geometry, QES, and method choice”Classify the four parameter pairs
then name the primary method and one independent check for a deep quartic, a generic noninteger Razavy well, and the first states of an integer Razavy well.
Solution
The conditions are independent:
| Geometry | Algebra | |
|---|---|---|
| single well | QES, | |
| double well | non-QES | |
| double well | QES | |
| single well | non-QES |
For a deep quartic at fixed local level, use its instanton/transseries condition and compare the Galerkin and coordinate-space spectra. For noninteger Razavy, use exact WKB or the DCHE connection problem and check a parity-resolved grid. For the first integer-Razavy states, use the finite Jacobi block and check the full coordinate operator. Near either barrier top, replace a fixed-level instanton formula by a uniform turning-point treatment.
References
Section titled “References”- J. Zinn-Justin and U. D. Jentschura, “Multi-Instantons and Exact Results I: Conjectures, WKB Expansions, and Instanton Interactions”, Annals of Physics 313 (2004), 197–267, arXiv:quant-ph/0501136, fixes the quartic normalization and its model-specific transseries data.
- E. Delabaere, H. Dillinger, and F. Pham, “Exact Semiclassical Expansions for One-Dimensional Quantum Oscillators”, Journal of Mathematical Physics 38 (1997), 6126–6184, supplies the exact-WKB foundation for analytic one-dimensional oscillators.
- B. Simon, “Semiclassical analysis of low lying eigenvalues. II. Tunnelling”, Annals of Mathematics 120 (1) (1984), 89–118, and B. Helffer and J. Sjöstrand, “Multiple Wells in the Semi-Classical Limit I”, Communications in Partial Differential Equations 9 (1984), 337–408, give rigorous action-controlled tunnelling results.
- M. Razavy, “An exactly soluble Schrödinger equation with a bistable potential,” American Journal of Physics 48 (4) (1980), 285–288, doi:10.1119/1.12141, introduces the hyperbolic model and its finite low-state construction.
- F. Finkel, A. González-López, and M. A. Rodríguez, “On the families of orthogonal polynomials associated to the Razavy potential,” Journal of Physics A: Mathematical and General 32 (39) (1999), 6821–6835, doi:10.1088/0305-4470/32/39/308, arXiv:math-ph/9905020, provides the modern Razavy convention and invariant polynomial sector.
- NIST Digital Library of Mathematical Functions, §2.8, Differential Equations with a Parameter, supplies the coalescing-turning-point uniformization, §1.13(iv) fixes Liouville transformations, and §31.12, Confluent Forms of Heun’s Equation fixes the doubly confluent convention used in the global comparison.